17872-39-8Relevant academic research and scientific papers
Catalytic Cage Formation via Controlled Dimerization of Norbornadienes: An Entry to Functionalized HCTDs (Heptacyclo[6.6.0.02,6.03,13.04,11.05,9.010,14]tetradecanes)
Lim, Hee Nam,Dong, Guangbin
, p. 1104 - 1107 (2016)
A general and practical catalytic method has been developed for the rapid synthesis of HCTD (heptacyclo[6.6.0.02,6.03,13.04,11.05,9.010,14]tetradecanes) and various new 7,12-disubstituted HCTDs from n
The synthesis and characterization of bis(norbornadiene)dicarbonylmolybdenum. An intermediate of the metal-assisted dimerization of norbornadiene
Chow, Tahsin J.,Wu, Ming-Yu,Liu, Ling-Kang
, p. c33-c37 (2007/10/02)
Bis(norbornadiene)dicarbonylmolybdenum was isolated in a good yield during molybdenum-mediated dimerization of norbornadiene for the formation of heptacyclo[5.5.1.14,10.02,6.03,11.05,9.08,12]tetradecane. The carbon-to-metal bondings of the complex were examined by 1H and 13C NMR, and it was found that the chemical shifts of one double bond on each norbornadiene ligand are located significantly upfield from the other. The structure was analyzed by single crystal X-ray crystallography and an approximate 0.2 A difference in the metal-carbon bond distances was observed.
