17875-66-0Relevant academic research and scientific papers
Dirhodium(II) tetrakis(perfluorobutyrate)-catalyzed 1,4-hydrosilylation of α,β-unsaturated carbonyl compounds
Anada, Masahiro,Tanaka, Masahiko,Suzuki, Kanami,Nambu, Hisanori,Hashimoto, Shunichi
, p. 1622 - 1623 (2006)
The use of dirhodium(II) catalysts in the 1,4-hydrosilylation of α,β-unsaturated ketones and aldehydes was explored. Dirhodium(II) tetrakis(perfluorobutyrate), Rh2(pfb)4, proved to be the catalyst of choice for this process, providin
Synthesis of silyl monoperoxyketals by regioselective cobalt-catalyzed peroxidation of silyl enol ethers: Application to the synthesis of 1,2-dioxolanes
Hurlocker, Brisa,Miner, Matthew R.,Woerpel
supporting information, p. 4280 - 4283 (2014/10/15)
The cobalt-catalyzed peroxidation of silyl enol ethers with molecular oxygen and triethylsilane provided silyl monoperoxyketals in 54%-96% yield. These compounds serve as precursors to peroxycarbenium ions, which undergo annulations to provide 1,2-dioxola
