178757-76-1

Basic information

• Product Name: Acetic acid (2R,3R,4S,5R,6R)-3-acetoxy-2-acetoxymethyl-5-((2R,3R,4S,5R,6R)-4,5-diacetoxy-6-acetoxymethyl-3-benzyloxy-tetrahydro-pyran-2-yloxy)-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-4-yl ester
• Synonyms: Acetic acid (2R,3R,4S,5R,6R)-3-acetoxy-2-acetoxymethyl-5-((2R,3R,4S,5R,6R)-4,5-diacetoxy-6-acetoxymethyl-3-benzyloxy-tetrahydro-pyran-2-yloxy)-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-4-yl ester
• CAS NO: 178757-76-1
• Molecular Weight: 829.036
• Mol File: 178757-76-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Acetic acid (2R,3R,4S,5R,6R)-3-acetoxy-2-acetoxymethyl-5-((2R,3R,4S,5R,6R)-4,5-diacetoxy-6-acetoxymethyl-3-benzyloxy-tetrahydro-pyran-2-yloxy)-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-4-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid (2R,3R,4S,5R,6R)-3-acetoxy-2-acetoxymethyl-5-((2R,3R,4S,5R,6R)-4,5-diacetoxy-6-acetoxymethyl-3-benzyloxy-tetrahydro-pyran-2-yloxy)-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-4-yl ester(178757-76-1)
• EPA Substance Registry System: Acetic acid (2R,3R,4S,5R,6R)-3-acetoxy-2-acetoxymethyl-5-((2R,3R,4S,5R,6R)-4,5-diacetoxy-6-acetoxymethyl-3-benzyloxy-tetrahydro-pyran-2-yloxy)-6-(2,2,2-trichloro-acetimidoyloxy)-tetrahydro-pyran-4-yl ester(178757-76-1)

Safety Data

• Hazardous Substances Data: 178757-76-1(Hazardous Substances Data)

Upstream product

• 13036-15-2 1,3,4,6-tetra-O-acetyl-β-D-glucopyranose 
• 178757-74-9 Acetic acid (2S,3R,4S,5R,6R)-2,5-diacetoxy-6-acetoxymethyl-3-((2R,3R,4S,5R,6R)-4,5-diacetoxy-6-acetoxymethyl-3-benzyloxy-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-4-yl ester 
• 55287-65-5 3,4,6-tri-O-acetyl-2-O-benzyl-β-D-glucopyranosyl chloride 
• 545-06-2 trichloroacetonitrile 

Relevant articles and documents

Synthesis and X-ray crystallographic study of cyclobis-(1 → 2)-α-D-glucopyranosyl peracetate

Treatment of O-(3,4,6-tri-O-acetyl-2-O-benzyl- α-D-glucopyranosyl)-(1 → 2)-3,4,6-tri-O-acetyl-α-D-glucopyranosyl trichloroacetimidate with BF3·Et2O gave a high yield of the peracetate of cyclobis-(1 → 2)-α-D-glucopyranosyl (6). Compound 6 crystallizes in the space group P21, [a = 6.888(2), b = 24.771(5), c = 9.105(2) A, β = 111.49(2)°, Z = 2] and shows a high degree of symmetry. In 6 the two α-D-glucopyranosyl residues are in a slightly distorted chair conformation. The glucose moieties are interconnected by a 1,4-dioxane moiety which is in a boat conformation, with the anomeric carbon atoms in the bow positions.