178763-22-9Relevant academic research and scientific papers
Asymmetric Heck reaction-carbanion capture process. Catalytic asymmetric total synthesis of (-)-Δ(9(12))-capnellene
Ohshima, Takashi,Kagechika, Katsuji,Adachi, Midori,Sodeoka, Mikiko,Shibasaki, Masakatsu
, p. 7108 - 7116 (1996)
An asymmetric Heck reaction-carbanion capture process was realized for the first time, making possible the catalytic asymmetric synthesis of various functionalized bicyclo[3.3.0]octane derivatives 6 in up to 94% ee. Sodium bromide had interesting effects
Synthesis of the tricyclic core of 5α-capnellenols using asymmetric Heck reaction-carbanion capture process
Itano, Wataru,Ohshima, Takashi,Shibasaki, Masakatsu
, p. 3053 - 3056 (2008/02/13)
The tricyclic core of 5α-capnellenols was synthesized using an asymmetric Heck reaction-carbanion capture process and an intramolecular nitrile oxide cycloaddition as key ring construction steps. Moreover, the desired C5-α-OH product was obtained through
