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Rh(P(CH3)3)2(Si(CH3)3)((CH3)2SiC(C6H5)C(C6H5)Si(CH3)Si(CH3)3) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

178820-67-2

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178820-67-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 178820-67-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,7,8,8,2 and 0 respectively; the second part has 2 digits, 6 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 178820-67:
(8*1)+(7*7)+(6*8)+(5*8)+(4*2)+(3*0)+(2*6)+(1*7)=172
172 % 10 = 2
So 178820-67-2 is a valid CAS Registry Number.

178820-67-2Downstream Products

178820-67-2Relevant academic research and scientific papers

Migrations in a polysilyl complex of rhodium. Trapping of an apparent silylene intermediate and observation of reversible Si-Si bond reductive elimination

Mitchell, Gregory P.,Tilley, T. Don

, p. 3477 - 3479 (1996)

Reaction of (Me3P)3RhCl with (THF)3LiSi-(SiMe3)3 in the presence of 2-butyne or diphenylacetylene generates (Me3P)2(Me3Si)RhSiMe 2C(R)=C(R)SiMe(SiMe3) (1, R = Me; 2, R= Ph). These complexes undergo a fluxional process which exchanges the SiMe3 groups, apparently by Si-Si bond reductive elimination / oxidative addition.

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