17883-47-5Relevant academic research and scientific papers
ULTRAVIOLET SPECTROSCOPIC INVESTIGATION OF ISOCYANATO- AND ISOTHIOCYANATO SILANES CONTAINING PHENYL- AND METHYL GROUPS
Veszpremi, Tamas,Barta, Istvan,Nagy, Jozsef
, p. 243 - 250 (2007/10/02)
The members of the series R(n)Si(NCO)(4-n) and R(n)Si(NCS)(4-n), where R = -CH3 and -C6H5, were prepared, their ultraviolet spectra recorded and the observed bands assigned.The spectra were compared to those of halogeno derivatives.The similarity of halogen- and pseudohalogeno-groups and difference between the effect of methyl- and phenyl-groups were studied.
Chemical process
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, (2008/06/13)
Optionally substituted silicon isocyanates are prepared by reacting a corresponding silicon halide with an alkali metal cyanate or an alkaline earth metal cyanate in an inert solvent having a dielectric constant below about 10, in the presence of a crown ether as a catalyst.
