178875-14-4Relevant articles and documents
From thiophene S-oxides to 7-thiabicyclo[2.2.1]hept-5-enes
Li, Yuan-Qiang,Thiemann, Carolin,Ohira, Daisuke,Mataka, Shuntaro,Tashiro, Masashi,Thiemann, Thies
, p. 702 - 704 (2009)
Oligocycles with a 7-thiabicyclo[2.2.1]hept-5-ene unit have been prepared stereoselectively by cycloaddition of thiophene S-oxides to alkenes and subsequent deoxygenation of the sulfoxy bridge of the cycloadducts with PBr 3.
Lewis Acid Catalysis in the Oxidative Cycloaddition of Thiophenes
Li, Yuanqiang,Thiemann, Thies,Sawada, Tsuyoshi,Mataka, Shuntaro,Tashiro, Masashi
, p. 7926 - 7936 (1997)
Thiophenes 1 were treated with m-chloroperbenzoic acid (m-CPBA) under BF3·Et2D catalysis to afford thiophene S-monoxides. These could be reacted in situ as intermediary species with a number of dienophiles to provide arenes (with alk