17893-93-5Relevant academic research and scientific papers
Dehydrogenative diels-alder reaction
Ozawa, Takuya,Kurahashi, Takuya,Matsubara, Seijiro
supporting information; experimental part, p. 5390 - 5393 (2011/12/04)
The dehydrogenative cycloaddition of dieneynes, which possess a diene in the form of a styrene moiety and a dienophile in the form of an alkyne moiety, produces naphthalene derivatives when heated. It was found that a key requirement of this process is th
Synthesis and reactivity of a 9-membered azaenediyne: Importance of proximity effect in N-alkylation
Roy, Sandip Kumar,Basak, Amit
, p. 1646 - 1648 (2008/02/08)
Synthesis of a 9-membered azaenediyne has been achieved for the first time via intramolecular N-alkylation; the importance of proximity of the reacting centres via cobalt carbonyl complexation of the acetylenic moiety and not the activation of propargylic
Nickel-catalyzed cocyclotrimerization of arynes with diynes; a novel method for synthesis of naphthalene derivatives
Hsieh, Jen-Chieh,Cheng, Chien-Hong
, p. 2459 - 2461 (2007/10/03)
The NiBr2(dppe)-Zn system effectively catalyzes the [2 + 2 + 2] cocyclotrimerization of arynes with diynes, leading to substituted naphthalene derivatives in moderate to good yields. This cocyclotrimerization reaction shows excellent tolerance of functional groups and leads to products of 5- to 7-membered fused-ring sizes. The Royal Society of Chemistry 2005.
