178943-94-7

Basic information

• Product Name: Me₃P=NCH₂Ph
• Synonyms: Me₃P=NCH₂Ph
• CAS NO: 178943-94-7
• Molecular Weight: 181.217
• Mol File: 178943-94-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Me₃P=NCH₂Ph(CAS DataBase Reference)
• NIST Chemistry Reference: Me₃P=NCH₂Ph(178943-94-7)
• EPA Substance Registry System: Me₃P=NCH₂Ph(178943-94-7)

Safety Data

• Hazardous Substances Data: 178943-94-7(Hazardous Substances Data)

Upstream product

• 622-79-7 benzyl azide 
• 594-09-2 trimethylphosphane 

Downstream Products

• 1126780-00-4 N-benzyl-N-[trimethyl(phenylselenyl)phosphoranyl]octadecanamide 
• 1126780-15-1 N-benzyl-N-[trimethyl(phenylselenyl)phosphoranyl]-3-phenylpropanamide 
• 1126780-09-3 N-benzyl-N-[trimethyl(2-pyridylselenyl)phosphoranyl]-3-phenylpropanamide 
• 1126779-95-0 C₃₃H₅₅N₂OPS 
• 1126779-86-9 N-benzyl-N-[trimethyl(2-pyridylselenyl)phosphoranyl]octadecanamide 
• 39896-97-4 benzyl-carbamic acid benzyl ester 
• 42116-44-9 N-tert-butoxycarbonylbenzylamine 

Relevant articles and documents

One-pot conversion of azides to Boc-protected amines with trimethylphosphine and Boc-ON

Reaction of azides with trimethylphosphine followed by addition of 2- (tert-butoxycarbonyloxyimino)-2-phenyl-acetonitrile (Boc-ON) at -20°C and stirring at r.t. for 5 h affords the desired Boc-amines in 87-100% yields. Similar types are obtained by mixing

A practical procedure for the preparation of carbamates from azides

A practical procedure for the direct conversion of azides to carbamates has been found. High yields are obtained when primary and secondary aliphatic azides, as well as α-azido esters, are treated in THF with Me3P and several chloroformates (ClCOOBn, ClCOOMe, ClCOOEt, ClCOOCH2CCl3, ClCOOCH2CH=CH2).