178970-77-9Relevant academic research and scientific papers
Reactions of Ethyl 5,6,7,8-Tetrafluoro-4-oxo-4H-1-benzopyran-2-carboxylate with N-(2-Aminoethyl)ethylenediamine and N-(2-Hydroxyethyl)ethylenediamine
Saloutin, V. I.,Bazyl', I. T.,Skryabina, Z. E.,Kodess, M. I.,Chupakhin, O. N.
, p. 1293 - 1297 (2007/10/03)
Ethyl 5,6,7,8-tetrafluoro-4-oxo-4H-1-benzopyran-2-carboxylate reacts with N-(2-aminoethyl)ethylenediamine and N-(2-hydroxyethyl)ethylenediamine, forming derivatives of pyrazinopyrazine and 4-(2-hydroxyethyl)piperazin-2-one, respectively.The structure of the products was proved by IR and 1H and 19F NMR spectroscopy and chemical transformations.A stable salt of pyrazinopyrazine with trifluoroacetic acid was isolated.
