179007-08-0Relevant articles and documents
Synthesis of phenanthridinones from N-methoxybenzamides and aryltriethoxysilanes through RhIII-catalyzed C-H and N-H bond activation
Senthilkumar, Natarajan,Parthasarathy, Kanniyappan,Gandeepan, Parthasarathy,Cheng, Chien-Hong
, p. 2175 - 2181 (2013)
An efficient method for the one-pot synthesis of substituted phenanthridinone derivatives from N-methoxybenzamides and aryltriethoxysilanes through rhodium-catalyzed dual C-H bond activation and annulation reactions is described. A double-cycle mechanism is proposed to account for this catalytic reaction. In addition, isotope-labeling studies were performed to understand the intimate mechanism of the reaction. Keeping active: The rhodium-catalyzed C-H bond activation and annulation reactions of N-methoxybenzamides with aryltriethoxysilanes to give substituted phenanthridinone derivatives in good-to-excellent yields is described. Copyright