17933-75-4

Basic information

• Product Name: ph2Si(Oet-2-Cl)2
• Synonyms: ph2Si(Oet-2-Cl)2
• CAS NO: 17933-75-4
• Molecular Weight: 341.309
• Mol File: 17933-75-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ph2Si(Oet-2-Cl)2(CAS DataBase Reference)
• NIST Chemistry Reference: ph2Si(Oet-2-Cl)2(17933-75-4)
• EPA Substance Registry System: ph2Si(Oet-2-Cl)2(17933-75-4)

Safety Data

• Hazardous Substances Data: 17933-75-4(Hazardous Substances Data)

Upstream product

• 775-12-2 diphenylsilane 
• 107-07-3 2-chloro-ethanol 
• 75-21-8 oxirane 
• 80-10-4 diphenylsilyl dichloride 

Relevant articles and documents

Dehydrogenative Coupling of Hydrosilanes and Alcohols by Alkali Metal Catalysts for Facile Synthesis of Silyl Ethers

Cross-dehydrogenative coupling (CDC) of hydrosilanes with hydroxyl groups, using alkali metal hexamethyldisilazide as a single-component catalyst for the formation of Si-O bonds under mild condition, is reported. The potassium salt [KN(SiMe3)2] is highly efficient and chemoselective for a wide range of functionalized alcohols (99% conversion) under solvent-free conditions. The CDC reaction of alcohols with silanes exhibits first-order kinetics with respect to both catalyst and substrate concentrations. The most plausible mechanism for this reaction suggests that the initial step most likely involves the formation of an alkoxide followed by the formation of metal hydride as active species.