1795-26-2

Usage

Uses

Used in Chemical Industry:
CIS,CIS,TRANS-1,3,5-TRIMETHYLCYCLOHEXANE is used as a starting material in organic synthesis for the production of various chemical products. Its unique structure and properties make it suitable for creating a range of compounds in the chemical industry.
Used in Fragrance and Flavoring Production:
In the fragrance and flavoring industry, CIS,CIS,TRANS-1,3,5-TRIMETHYLCYCLOHEXANE is used as a key component in the synthesis of various scents and tastes. Its ability to be modified and combined with other compounds allows for the creation of diverse and complex fragrances and flavorings.
Used as a Solvent in Chemical Reactions:
CIS,CIS,TRANS-1,3,5-TRIMETHYLCYCLOHEXANE is employed as a solvent in a variety of chemical reactions due to its solubility in organic solvents and its ability to dissolve a wide range of compounds. This makes it a versatile and valuable component in many industrial processes.

InChI:InChI=1/C9H18/c1-7-4-8(2)6-9(3)5-7/h7-9H,4-6H2,1-3H3/t7-,8-,9-

Upstream product

• 108-67-8 1,3,5-trimethyl-benzene 
• 3643-64-9 1,3,5-trimethylcyclohexene 

Relevant academic research and scientific papers

Polysilane-Immobilized Rh-Pt Bimetallic Nanoparticles as Powerful Arene Hydrogenation Catalysts: Synthesis, Reactions under Batch and Flow Conditions and Reaction Mechanism

Hydrogenation of arenes is an important reaction not only for hydrogen storage and transport but also for the synthesis of functional molecules such as pharmaceuticals and biologically active compounds. Here, we describe the development of heterogeneous Rh-Pt bimetallic nanoparticle catalysts for the hydrogenation of arenes with inexpensive polysilane as support. The catalysts could be used in both batch and continuous-flow systems with high performance under mild conditions and showed wide substrate generality. In the continuous-flow system, the product could be obtained by simply passing the substrate and 1 atm H2 through a column packed with the catalyst. Remarkably, much higher catalytic performance was observed in the flow system than in the batch system, and extremely strong durability under continuous-flow conditions was demonstrated (>50 days continuous run; turnover number >3.4 × 105). Furthermore, details of the reaction mechanisms and the origin of different kinetics in batch and flow were studied, and the obtained knowledge was applied to develop completely selective arene hydrogenation of compounds containing two aromatic rings toward the synthesis of an active pharmaceutical ingredient.

Catalytic hydrogenation of aromatics under biphasic conditions: Isolation and structural characterisation of the cluster intermediate [(η6-C6Me6)2(η 6-C6H6)Ru3(μ2-H) 2(μ2-OH)(μ3-O)]+

The water-soluble cluster cation [(η6-C6Me6)2(η 6-C6H6)Ru3(μ2-H) 3(μ3-O)]+ (2) catalyses the hydrogenation of benzene and benzene derivatives to give the corresponding cyclohexanes under biphasic conditions. The catalytic activity of 2 depends markedly on the substrate, an extremely high activity being observed for ethylbenzene. The cationic species present in the catalytic mixture of the ethylbenzene hydrogenation could be isolated as the tetrafluoroborate salt and characterised as the cation [(η6-C6Me6)2(η 6-C6H6)Ru3(μ2-H) 2(μ2-OH)(μ3-O)]+ (3). With 3 as the catalyst, the catalytic activity is also much higher for other benzene derivatives.