179536-77-7

Basic information

• Product Name: (4aS,5S,8aS,10aR)-5-Benzenesulfonylmethyl-2,2-dimethyl-decahydro-1,3-dioxa-4b-aza-phenanthrene
• Synonyms: (4aS,5S,8aS,10aR)-5-Benzenesulfonylmethyl-2,2-dimethyl-decahydro-1,3-dioxa-4b-aza-phenanthrene
• CAS NO: 179536-77-7
• Molecular Weight: 379.521
• Mol File: 179536-77-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (4aS,5S,8aS,10aR)-5-Benzenesulfonylmethyl-2,2-dimethyl-decahydro-1,3-dioxa-4b-aza-phenanthrene(CAS DataBase Reference)
• NIST Chemistry Reference: (4aS,5S,8aS,10aR)-5-Benzenesulfonylmethyl-2,2-dimethyl-decahydro-1,3-dioxa-4b-aza-phenanthrene(179536-77-7)
• EPA Substance Registry System: (4aS,5S,8aS,10aR)-5-Benzenesulfonylmethyl-2,2-dimethyl-decahydro-1,3-dioxa-4b-aza-phenanthrene(179536-77-7)

Safety Data

• Hazardous Substances Data: 179536-77-7(Hazardous Substances Data)

Upstream product

• 179536-76-6 (4aS,6S,8aR)-6-((E)-5-Benzenesulfonyl-pent-4-enyl)-2,2-dimethyl-hexahydro-[1,3]dioxino[5,4-b]pyridine-5-carboxylic acid 2,2,2-trichloro-ethyl ester 
• 56069-39-7 diethyl phenylsulfonylmethylphosphonate 
• 179536-73-3 2-((4aS,6R,8aR)-5-Benzyl-2,2-dimethyl-hexahydro-[1,3]dioxino[5,4-b]pyridin-6-yl)-ethanol 
• 179536-74-4 ethyl (4aS,6R,8aR)-(+)-hexahydro-2,2-dimethyl-5-(phenylmethyl)-4H-1,3-dioxino-[5,4-b]pyridine-6-but-(2E)-enoate 

Downstream Products

• 179536-79-9 (3R,4S,6S,9aS)-(-)-{[(2,2-dimethyl)diphenylsiloxy]methyl}-3-(methoxymethoxy)-6-(phenylsulfonylmethyl)octahydro-2H-quinolizine 
• 179536-78-8 (3R,4S,6S,9aS)-(-)-4-{[(2,2-dimethylethyl)diphenylsiloxy]methyl}-3-hydroxy-6-(phenylsulfonylmethyl)-octahydro-2H-quinolizine 
• 179536-80-2 (3R,4S,6S,9aS)-(-)-4-(hydroxymethyl)-3-(methoxymethoxy)-6-(phenylsulfonylmethyl)-octahydro-2H-quinolizine 
• 179536-81-3 (3R,4S,6S,9aS)-(+)-4-(iodomethyl)-3-(methoxymethoxy)-6-(phenylsulfonylmethyl)-octahydro-2H-quinolizine 
• 179536-82-4 (3R,4S,6S,9aS)-(-)-3-(methoxymethoxy)-4-methyl-6-(phenylsulfonylmethyl)-octahydro-2H-quinolizine 
• 132621-83-1 (-)-clavepictine A 
• 132621-84-2 (3R,4S,6S,9aS)-6-((1E,3E)-deca-1,3-dienyl)-4-methyl-octahydro-quinolizin-3-ol 
• 1053244-37-3 (3R,4S,6S,9aS)-6-Benzenesulfonylmethyl-4-hydroxymethyl-octahydro-quinolizin-3-ol 

Relevant articles and documents

Total synthesis of clavepictines A and B. Diastereoselective cyclization of δ-aminoallenes

The stereocontrolled total synthesis of (-)-clavepictine A (1A) and (+)- clavepictine B (1B) has been accomplished in an enantioselective fashion, which has unequivocally established the absolute configuration of 1A and 1B. The pivotal step in the synthes

Enantioselective total synthesis of the marine alkaloid clavepictines A and B

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