179676-03-0Relevant articles and documents
Organomercury( II) and organotin( IV) compounds with nitrogen-containing substituents
Bonnardel,Parish
, p. 221 - 232 (2007/10/03)
New compounds of the type ArHgCl, ArCH2HgCl, Ar2Hg, (ArCH2)2Hg, ArSnPh3 and ArCH2SnPh3 are described. The aryl groups carry various substituents, but all have a group in the 2-position which involves a nitrogen atom which could in principle coordinate to the metal atom, e.g. -NMe2, -CH2NMe2, -CONH2, -NHCOtBu, -SO2NMe2, -oxaz (oxaz = 4,4-dimethyl-2-oxazoline). Full 1H and 13C NMR assignments are made for all the compounds; the data provide no evidence for N → Hg coordination in solution. IR data suggest that such interaction is, at most, very weak in the solids.