179736-41-5Relevant academic research and scientific papers
Reactions of orthomanganated aryl ketones with PhNSO and related species: A new route to orthomanganated imines
Cooney, Janine M.,Main, Lyndsay,Nicholson, Brian K.
, p. 191 - 197 (1996)
PhN=S=O reacts with some orthomanganated acetophenones to replace the ketone oxygen with a Ph-N group, so generating the corresponding orthomanganated imine. No insertion into the Mn-C bond was observed, in contrast to analogous reactions of SO2. The related PhS(O)2N=S=O or (PhS(O)2N=)2S did not react under the same conditions. The X-ray crystal structure of one of the new imine complexes, η2-3-chloro-2-[1-(N-phenylimino)ethyl]phenyltetracarbonylmanganese, was determined.
