17978-77-7

Basic information

• Product Name: PR(FOD)3
• Synonyms: praseodymium,tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato-o,o;RONDEAU'S REAGENT;RESOLVE-AL(TM) PRFOD;PRASEODYMIUM(FOD);PRASEODYMIUM (FOD)3;PRASEODYMIUM/HEPTAFLUORODIMETHYL-OCTANEDIONE COMPLEX;PRASEODYMIUM III 6,6,7,7,8,8,8-HEPTA-FLUORO-2,2-DIMETHYL-3,5-OCTANEDIONATE;PRASEODYMIUM(III) TRIS(6,6,7,7,8,8,8-HEPTAFLUORO-2,2-DIMETHYL-3,5-OCTANEDIONATE)
• CAS NO: 17978-77-7
• Molecular Formula: C30H30F21O6Pr
• Molecular Weight: 1026.43
• EINECS: 241-902-6
• Product Categories: Classes of Metal Compounds;Pr (Praseodymium) Compounds;Transition Metal Compounds;Other Metal
• Mol File: 17978-77-7.mol
• Article Data: 0

Chemical Properties

• Melting Point: 215-219 °C(lit.)
• Boiling Point: 130°C 0,01mm
• Flash Point: 75.5°C
• Appearance: light green/Powder
• Density: g/cm³
• Vapor Pressure: 0.0812mmHg at 25°C
• Solubility: Soluble in hexane, methanol, tetrahydrofuran.
• Sensitive: Hygroscopic
• CAS DataBase Reference: PR(FOD)3(CAS DataBase Reference)
• NIST Chemistry Reference: PR(FOD)3(17978-77-7)
• EPA Substance Registry System: PR(FOD)3(17978-77-7)

Safety Data

• Statements: 36/37/38
• Safety Statements: 24/25
• WGK Germany: 3
• TSCA: No
• Hazardous Substances Data: 17978-77-7(Hazardous Substances Data)

Usage

Chemical Properties

light green fine crystalline powder

Uses

Tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)praseodymium(III) is an NMR shift reagent. Being a lanthanide Tris(β-?diketonate), Tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)praseodymium(III) is used as a probe for chirality determination of biological amino alcohols via ligand-to-ligand chirality transfer.

InChI:InChI=1/3C10H11F7O2.Pr/c3*1-7(2,3)5(18)4-6(19)8(11,12)9(13,14)10(15,16)17;/h3*4,18H,1-3H3;/q;;;+3/p-3/b3*5-4-;