17983-33-4

Basic information

• Product Name: 1-allyldimethylsilyl-4-bromobenzene
• Synonyms: 1-allyldimethylsilyl-4-bromobenzene
• CAS NO: 17983-33-4
• Molecular Weight: 255.23
• Mol File: 17983-33-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1-allyldimethylsilyl-4-bromobenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-allyldimethylsilyl-4-bromobenzene(17983-33-4)
• EPA Substance Registry System: 1-allyldimethylsilyl-4-bromobenzene(17983-33-4)

Safety Data

• Hazardous Substances Data: 17983-33-4(Hazardous Substances Data)

Upstream product

• 4028-23-3 Allylchlorodimethylsilane 
• 106-37-6 1.4-dibromobenzene 
• 18236-77-6 (4-bromophenyl)chlorodimethylsilane 
• 106-95-6 allyl bromide 

Downstream Products

• 261761-38-0 4-(allyldimethylsilyl)benzaldehyde 
• 288372-27-0 4-allyldimethylsilylphenethyl alcohol 
• 247566-27-4 4-allyldimethylsilylbenzyl alcohol 
• 247566-28-5 4-allyldimethylsilylbenzyl bromide 
• 288372-08-7 (2Z)-methyl-2-acetamido-3-([4-allyldimethylsilyl]phenyl)prop-2-enoate 
• 288372-19-0 4-allyldimethylsilylphenylacetataldehyde 
• 288372-41-8 N-Boc-4-allyldimethylbenzylamine 
• 359792-68-0 (S)-(+)-N-(4-allyldimethylsilylbenzylidene)-p-toluenesulfonamide 
• 288372-09-8 (S)-methyl-2-acetamido-3-([4-allyldimethylsilyl]phenyl)propanoate 
• 288372-20-3 (2Z)-methyl-2-acetamido-4-([4-allyldimethylsilyl]phenyl)but-2-enoate 
• 288372-21-4 (S)-methyl-2-acetamido-4-([4-allyldimethylsilyl]phenyl)butanoate 
• 288372-10-1 (S)-methyl-3-([4-allyldimethylsilyl]naphthyl)-2-(tert-butoxycarbamido)propanoate 
• 288372-40-7 {[4-(allyl-dimethyl-silanyl)-benzyl]-tert-butoxycarbonyl-amino}-oxo-acetic acid ethyl ester 
• 359792-69-1 (S_R,R)-(+)-methyl 3-(p-tolylsulfinamido)-3-([4-allyldimethylsilyl]phenyl)propanoate 

Relevant articles and documents

Silicon-based aromatic transferring linkers for traceless solid-phase synthesis of aryl-, polyaryl-, and heteroaryl-containing compounds

A number of arylsilane-based linkers are prepared for traceless solid-phase synthesis. General methodologies for introduction of the silyl group and various functional groups to aromatic, polyaromatic, and heteroaromatic rings are developed. Also, broad u

Rapid, high-yield, solid-phase synthesis of the antitumor antibiotic sansalvamide a using a side-chain-tethered phenylalanine building block

(matrix presented) A 10-step solid-phase synthesis of the cytotoxic depsipeptide sansalvamide A (1) has been accomplished in an overall yield of 67% with >95% purity employing polymer-bound phenylalanine building block 2. Both the N- and C-termini of 2 are extended followed by on-resin head-to-tail macrocyclization of the linear peptide in a high yield. This should be a general stategy for the synthesis of diverse libraries of cyclic peptides and depsipeptides that contain exclusively phenylalanine and other hydrophobic side chains.