17991-22-9

Basic information

• Product Name: 2-Butanone, 4-(4-methyl-1-naphthalenyl)-
• CAS NO: 17991-22-9
• Molecular Formula: C15H16O
• Molecular Weight: 212.291
• Mol File: 17991-22-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Butanone, 4-(4-methyl-1-naphthalenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butanone, 4-(4-methyl-1-naphthalenyl)-(17991-22-9)
• EPA Substance Registry System: 2-Butanone, 4-(4-methyl-1-naphthalenyl)-(17991-22-9)

Safety Data

• Hazardous Substances Data: 17991-22-9(Hazardous Substances Data)

Upstream product

• 76673-34-2 3-(4-methyl-1-naphthalenyl)propionic acid 
• 917-54-4 methyllithium 

Relevant articles and documents

The Formation of Bridged Bicyclic 1,2,4-Trioxanes by Intramolecular Capture of β-Hydroperoxy Cations

The 1,4-endoperoxide, prepared from 3-(4-methylnaphth-1-yl) propanal by photo-oxygenation in CH2Cl2, gave on treatment with Amberlyst-15, 3,10b-epidioxy-2,3,4a,10b-tetrahydro-6-methyl-1H-naphthopyran in 85percent yield.Its structure was determined by X-ray crystal structure analysis.The 1,2,4-trioxane moiety is locked in a twist-boat conformation with trans fusion to the parent six-membered ring.The 1,4-endoperoxides of the methyl, butyl, and phenyl ketone analogues of the aforementioned aldehyde underwent similar acid-catalyzed rearrangement to the corresponding bridged bicyclic trioxanes in 94,47, and 48percent yelds, respectively.