180006-74-0

Basic information

• Product Name: [η(5)-C5Ph4(p-tolyl)]Fe(CO)[P(OPh)3]
• CAS NO: 180006-74-0
• Molecular Weight: 853.757
• Mol File: 180006-74-0.mol

Chemical Properties

• CAS DataBase Reference: [η(5)-C5Ph4(p-tolyl)]Fe(CO)[P(OPh)3](CAS DataBase Reference)
• NIST Chemistry Reference: [η(5)-C5Ph4(p-tolyl)]Fe(CO)[P(OPh)3](180006-74-0)
• EPA Substance Registry System: [η(5)-C5Ph4(p-tolyl)]Fe(CO)[P(OPh)3](180006-74-0)

Safety Data

• Hazardous Substances Data: 180006-74-0(Hazardous Substances Data)

Upstream product

• 101-02-0 triphenyl phosphite 

Relevant articles and documents

New examples of Arbuzov rearrangements of coordinated phosphites initiated by metal-centred radicals

Reaction of the persistent, iron-centred radical {η5-C5Ph4(p-tolyl)}Fe(CO)2 · with tertiary phosphites P(OR)3 (R = Me, Et) results in the formation of the Arbuzov rearrangement products {η5-C5Ph4(p-tolyl)}Fe(CO)2R, {η5-C5Ph4(p-tolyl)}Fe(CO)2{PO(OR)2} and {η5-C5Ph4(p-tolyl)}Fe(CO){P(OR)3}{PO(OR)2}. For both phosphites, the metal-centred radicals {η5-C5Ph4(p-tolyl)}Fe(CO){P(OR)3} · appear to be intermediates in a process which involves initial, direct abstraction by {η5-C5Ph4(p-tolyl)}Fe(CO)2 · of an alkyl group R from the coordinated P(OR)3 of {η5-C5Ph4(p-tolyl)}Fe(CO){P(OR)3} ·, followed by interception of the 16-electron intermediate, {η5-C5Ph4(p-tolyl)}Fe(CO){PO(OR)2}, by CO and P(OR)3.