180134-75-2

Upstream product

• 180134-71-8 (1S,4aS,8aS)-2-Benzyloxy-1-((1S,2R)-1,3-bis-benzyloxy-2-methoxy-propyl)-5,8-dioxo-1,5,8,8a-tetrahydro-4H-naphthalene-4a-carboxylic acid methyl ester 
• 180467-16-7 (1S,4aS,8aR)-2-Benzyloxy-1-((1S,2R)-1,3-bis-benzyloxy-2-methoxy-propyl)-5,8-dioxo-1,5,8,8a-tetrahydro-4H-naphthalene-4a-carboxylic acid methyl ester 
• 116558-37-3 (Z)-(2R,3S)-1,3,5-Tris-benzyloxy-hepta-4,6-dien-2-ol 
• 180134-72-9 (4aS,8S,8aR)-7-Benzyloxy-8-((1S,2R)-1,3-bis-benzyloxy-2-methoxy-propyl)-1,4-dioxo-1,3,4,5,8,8a-hexahydro-2H-naphthalene-4a-carboxylic acid methyl ester 

Downstream Products

• 180134-76-3 (1S,4aS,8aR)-1-((1S,2R)-1,3-Bis-benzyloxy-2-methoxy-propyl)-5-methylene-2,8-dioxo-octahydro-naphthalene-4a-carboxylic acid methyl ester 

Relevant academic research and scientific papers

An efficient synthesis of functionalised decalin via cycloaddition reaction of D-glucose based dienes and 2-methoxycarbonyl-p-benzoquinone

The cycloaddition reaction of D-glucose based dienes 1 (b,c) with in-situ generated 2-methoxycarbonyl-p-benzoquinone 2 furnished cycloadducts 3 (a,b) with excellent stereo- and regiochemical control. The cyclo-adduct 3b on further transformations furnished functionalised decalin 7c in quantitative yield.