180139-02-0

Basic information

• Product Name: C₁₃H₁₁Cl₄NP₂
• Synonyms: C₁₃H₁₁Cl₄NP₂
• CAS NO: 180139-02-0
• Molecular Weight: 384.997
• Mol File: 180139-02-0.mol

Chemical Properties

• CAS DataBase Reference: C₁₃H₁₁Cl₄NP₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₃H₁₁Cl₄NP₂(180139-02-0)
• EPA Substance Registry System: C₁₃H₁₁Cl₄NP₂(180139-02-0)

Safety Data

• Hazardous Substances Data: 180139-02-0(Hazardous Substances Data)

Downstream Products

• 180139-06-4 C₁₃H₉Cl₂NP₂ 

Relevant articles and documents

Reaction of N-alkylpyredinium salts with phosphorus trichloride

1-Alkylpyridinium bromides 1 having activated N-methylene group react with phosphorus trichloride to give N-(dichlorophosphinomethylene)pyridinium ylides 2. The site of the reaction in 1,2-dialkylpyridinium halides 3 under these conditions is determined by the relative activation of 1- and 2-methylene groups; in the absence of sufficient activation of N-methylene group, reaction occurs at the 2-methylene group to give dichlorophosphinylated anhydrobases 5 and 11. 1,4-Dialkylpyridinium bromide 13 behaves analogously to give the corresponding dichlorophosphinylated anhydrobase 14.