18026-73-8Relevant articles and documents
Silver-promoted desilylation catalyzed by ortho- and allosteric cucurbiturils
Lu, Xiaoyong,Masson, Eric
supporting information; experimental part, p. 2310 - 2313 (2010/08/04)
Cucurbit[6]-, [7]-, and [8]uril can catalyze the silver(I)-promoted desilylation of trimethylsilylalkynyl-containing pseudorotaxanes by stabilizing a key π-alkynyl silver intermediate through favorable interactions between the metallic cation and the cavi
Preparation of a new class of cleavable surfactants based on the silicon-carbon bond
Noronha, Glenn,Nguyen, Khanhlinh T.
, p. 4935 - 4938 (2007/10/03)
The ability of silicon to direct electrophiles to the ipso-position is used in developing a new class of cleavable amphiphiles containing an acid labile silicon-carbon (aromatic) bond. The synthesis of these amphiphiles is carried out in four steps to yie