180292-90-4Relevant academic research and scientific papers
Lithiated γ-tosyl-substituted benzylmethallylamine: New γ-amino methallyl sulfone anions in organic synthesis
Alonso, Diego A.,Falvello, Larry R.,Mancheno, Balbino,Najera, Carmen,Tomas, Milagros
, p. 5004 - 5012 (2007/10/03)
The mono- and dilithiation of benzyl[2-(tosylmethyl)-2-propenyl]amine (9) with n-butyllithium at -78°C leads to the new allyl sulfone monoanion 10a and dianion 10b, respectively. The intermediate 10a reacts regioselectively at the α-position with respect
