1803239-46-4Relevant academic research and scientific papers
A hand [...] compound and its full configuration, its preparation method and application
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Paragraph 0039; 0040; 0044; 0045; 0050-0053, (2018/05/16)
The invention provide a preparation method for a chiral tertiary phosphine compound containing chiral sulfonamide and shown as formula (1). The method takes aldehyde (ketone) 2 and chiral sulfinamide 3 as raw materials, which react with a nucleophilic rea
Novel chiral sulfinamide phosphines: Valuable precursors to chiral β-aminophosphines
Chen, Peng,Su, Xiao,Zhou, Wei,Xiao, Yuanjing,Zhang, Junliang
, p. 2700 - 2706 (2016/05/10)
Starting from commercially available aldehyde and chiral tert-butanesulfinamide, a series of chiral sulfinamide phosphines (Xiao-Phos) were synthesized via a two-step condensation-nucleophilic addition procedure. In most cases, nucleophilic addition of th
Design, synthesis, and application of a chiral sulfinamide phosphine catalyst for the enantioselective intramolecular rauhut-currier reaction
Su, Xiao,Zhou, Wei,Li, Yangyan,Zhang, Junliang
supporting information, p. 6874 - 6877 (2015/06/02)
A novel class of chiral sulfinamide phosphine catalysts (Xiao-Phos) are reported, which can be easily prepared from inexpensive commercially available starting materials. The Xiao-Phos catalysts showed good performance in enantioselective intramolecular R
