180386-53-2Relevant academic research and scientific papers
Alkylation, insertion of isocyanides, and intramolecular rearrangement processes in azatantalacyclopentene complexes. X-ray crystal Structure of [TaCp*Me2(CHCHCMe2NAr-K2C,N)] (Cp* - η5-C5Me5
Galakhov, Mikhail V.,Gomez, Manuel,Gomez-Sal, Pilar,Velasco, Patricia
, p. 3552 - 3560 (2008/10/09)
Chloro methyl and dimethyl azatantalacyclopentene complexes were prepared. Reaction of 1a with dibenzylmagnesium leads to the monoalkylated complex. Anisotropic thermal parameters were used in the last cycles of refinement for the nonhydrogen atoms. All c
Insertion of CO and CNR into tantalum-methyl bonds of imido(pentamethylcyclopentadienyl)tantalum complexes. X-ray crystal structures of [TaCp*(NR)-Me{η2-C(Me)=NR}] and [TaCp*Cl(O){η2-C(Me)=NR}] (R = 2,6-Me2C6H
Gómez, Manuel,Gómez-Sal, Pilar,Jiménez, Gerardo,Martín, Avelino,Royo, Pascual,Sánchez-Nieves, Javier
, p. 3579 - 3587 (2008/10/08)
[TaCp*Cl2{N(2,6-Me2C6H 3)}] reacts with 2 equiv of LiMe at -78 °C to give the imido dimethyl complex TaCp*Me2{N(2,6-Me2C6H3)} (1) in almost quantitative yield, whereas
Gómez, Manuel,Gómez-Sal, Pilar,Jiménez, Gerardo,Martín, Avelino,Royo, Pascual,Sánchez-Nieves, Javier
, p. 3579 - 3587 (2008/10/08)
[TaCp*Cl2{N(2,6-Me2C6H 3)}] reacts with 2 equiv of LiMe at -78 °C to give the imido dimethyl complex TaCp*Me2{N(2,6-Me2C6H3)} (1) in almost quantitative yield, whereas
