180387-17-1Relevant academic research and scientific papers
Stereoselective synthesis of alcohols, XLIX: Tetrahydro-4-pyranols and 4-piperidinols by intramolecular allylboration reaction
Hoffmann, Reinhard W.,Hense, Achim
, p. 1283 - 1288 (2007/10/03)
trans- and cis-3-Vinyltetrahydropyran-4-ol (11) and (12) as well as derivatives of trans- and cis-3-vinyl-4-piperidinol (25) and (33) were synthesized by essentially stereospecific intramolecular allylboration reactions: The (Z)-allylboronates 15 and 32 were converted into the cis-disubstituted heterocycles, the (E)-allylboronates 9 and 23 into the trans-disubstituted heterocycles. VCH Verlagsgesellschaft mbH, 1996.
