18043-74-8Relevant articles and documents
Mechanism of olefin hydrosilylation catalyzed by [RuCl(NCCH3)5]+: A DFT study
Tuttle, Tell,Wang, Dongqi,Thiel, Walter,K?hler, Jutta,Hofmann, Marco,Weis, Johann
, p. 2282 - 2290 (2007)
The hydrosilylation reaction between methyldimethoxysilane and methylvinyldimethoxysilane, catalyzed by the cationic species chloropenta(acetonitrile)ruthenium(II)+ (C1), was investigated with density functional theory (DFT). The Chalk-Harrod,
CONVENIENT LABORATORY SYNTHESIS OF VINYLIC SILICON COMPOUNDS VIA THE REACTIONS OF ACETYLENE WITH HYDROSILANES CATALYZED BY GROUP-VIII METAL PHOSPHINE COMPLEXES
Watanabe, Hamao,Asami, Muneo,Nagai, Yoichiro
, p. 363 - 374 (2007/10/02)
The hydrosilylation of acetylene (HCCH) with trichlorosilane, triethoxysilane, methyldichlorosilane, methyldiethoxysilane and -hexyldichlorosilane in an inert solvent in the presence of various phosphine complexes of Group-VIII metals such as Ru, Rh, Pd and Pt, as well as chloroplatinic acid, was investigated.Among the complexes studied, RuCl2(PPh3)3, PtCl2(PPh3)2, RhCl(PPh3)3, RhH(PPh3)4 and Pt(PPh3)4 were found to be the catalysts of choice for the selective syntheses of vinyltrichlorosilane, vinyltriethoxysilane, methylvinyldichlorosilane, methylvinyldiethoxysilane and -hexylvinyldichlorosilane, respectively.