180571-86-2Relevant academic research and scientific papers
Synthesis and characterisation of (η5-cyclopentadienyl)(η5-ring)titanium alkyl (ring = indenyl or C5H4But) complexes. Crystal and molecular structure of racemic [Ti(η5-C5H5)(η5-C 9H7)(CH2SiMe3)CI]
Hart, Suzanne L.,Duncalf, David J.,Hastings, Jeremy J.,McCamley, Andrew,Taylor, Paul C.
, p. 2843 - 2849 (2007/10/03)
New, selective and high-yielding preparations of the mixed-ring complexes [Ti(η5-C5H5)(η5-C 9H7)Cl2] and [Ti(η5-C5H5)(η5-C 5H4But)Cl2] are reported. These have been used to prepare a range of mono- and di-substituted titanium(IV) alkyl and benzenethiolate complexes of the form [Ti(η5-C5H5)(η 5-ring)(CH2SiMe3)Cl] and [Ti(η5-C5H5)(η5-ring)R 2] (ring = indenyl or C5H4But; R = Me, CH2Ph, CH2SiMe3 or SPh). While the indenyl ligand in the racemic, chiral-at-metal complex [Ti(η5-C5H5)(η5-C 9H7)(CH2SiMe3)Cl] is bound in an η5 fashion, X-ray structural data clearly indicate that there is some 'η3 ring-slip' character to the bonding. The NMR and nuclear Overhauser effect experiments conducted on [Ti(η5-C5H5)(η5-C 5H4But)(CH2SiMe3)Cl] demonstrate hindered rotation around the Ti-C5H4But bond and show the geometry to be fixed such that the But and SiMe3 groups are remote.
