180587-99-9Relevant academic research and scientific papers
(Trimethylstannyl)vinyl cuprates: Generation and conjugate addition reactions
Pereira, Oswy Z.,Chan, Tak-Hang
, p. 5406 - 5413 (2007/10/03)
A new convenient route to the bis[(trimethylstannyl)vinyl] cuprate reagent 9 is described. Its addition to α,β-unsaturated ketones has been studied. Bis(trimethylsilyl)acetamide (BSA) was found to activate 1,4-conjugate addition of 9 to α,β-unsaturated ketone esters without concomitant reduction of the double bond.
