180692-05-1

Upstream product

• 128014-10-8 (R)-(+)-t-butyl(phenyl)phosphinic bromide 
• 100-46-9 benzylamine 
• 6057-79-0 (S)-(-)-t-butyl(phenyl)phosphine oxide 
• 128014-09-5 tert-butyl(phenyl)phosphonic acid bromide 

Downstream Products

• 67253-72-9 (R)-(-)-P-t-butyl-P-phenyl-N-phosphoramidate 

Relevant academic research and scientific papers

Stereoselective addition of Grignard reagents to new P-chirogenic N-phosphinoylimines

The addition of various Grignard reagents to P-t-butyl-P-phenyl-N- phosphinoyl benzaldimine provides a stereoselective method for the synthesis of chiral phosphinoylamines. The Royal Society of Chemistry.

Preparation of bi- and tridentate doubly P-chiral diphosphine dioxide ligands for asymmetric catalysis

Syntheses of bi-and tridentate doubly P-chiral diphosphine dioxides through reaction of the individual enantiomers of optically pure lithiated tert-butylphenylphosphine oxide with different bifunctional electrophiles are described.