180720-30-3

Upstream product

• 180720-13-2 (S)-1-(N-tosyl-S-phenylsulfonimidoyl)methylcyclohexanol 
• 42153-74-2 (+)-(S_S)-S-methyl-S-phenyl-N-(p-tolylsulphonyl)sulphoximine 
• 108-94-1 cyclohexanone 
• 102817-19-6 (S)-N-tosyl-S-phenyl-S-(1-cyclohex-1-enylmethyl)sulfoximine 

Relevant academic research and scientific papers

Diastereoselective reactions and rearrangements of chiral allylic sulfoximines

The nucleophilic and electrophilic chemistry of chiral allylic sulfominines and their alkyl sulfoximine counterparts are described including the synthesis of highly functionalised cyclopropanes derivatives. The synthesis of primary and secondary N-tosyl a

Palladium-catalyzed rearrangement of allylic sulfoximines: Application to the asymmetric synthesis of chiral allylic amines

The palladium(0)-catalyzed reactions of the primary and secondary allylic sulfoximines 7, 9, 11, 13, 15, 17, and 19 gives allylic sulfinamides without 1,3-allylic rearrangement. These compounds were not isolated but were converted to their corresponding N-tosyl allylic amines, primary and secondary 8, 10, 12, 14, 16, 18, and 20, respectively. In the case of the optically active secondary allylic sulfoximines 17 and 19, chiral N-tosyl allylic secondary amines were formed in high enantiomeric purities.