180744-02-9

Basic information

• Product Name: Silane, diphenylbis[(phenylthio)methyl]-
• CAS NO: 180744-02-9
• Molecular Formula: C26H24S2Si
• Molecular Weight: 428.694
• Mol File: 180744-02-9.mol

Chemical Properties

• CAS DataBase Reference: Silane, diphenylbis[(phenylthio)methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, diphenylbis[(phenylthio)methyl]-(180744-02-9)
• EPA Substance Registry System: Silane, diphenylbis[(phenylthio)methyl]-(180744-02-9)

Safety Data

• Hazardous Substances Data: 180744-02-9(Hazardous Substances Data)

Upstream product

• 1266779-32-1 bis[bis(phenylthio)methyl]diphenylsilane 
• 13307-75-0 (phenylthio)methyllithium 
• 80-10-4 diphenylsilyl dichloride 

Downstream Products

• 646997-49-1 ReBr(CO)3(C₆H₅SCH₂)2Si(C₆H₅)2 
• 646997-48-0 PtCl₂(C₆H₅SCH₂)2Si(C₆H₅)2 
• 61739-79-5 1-methyl-1,3,3-triphenyl-1,3-disilacyclobutane 
• 180744-11-0 methyldiphenyl<(phenylthio)(trimethylsilyl)methyl>silane 

Relevant articles and documents

Stereoselective formation of phenylthio groups substituted 1-metalla-3-titanacyclobutanes

Desulfurizative titanation of group 14 metal compounds bearing two or four bis(phenylthio)methyl groups with the low-valent titanium reagent Cp 2Ti[P(OEt)3]2 produced phenylthio groups substituted 1-metalla-3-titanacyclobu

New bis (lithiomethyl)silanes: building blocks for organosilanes

The first high yield preparation of non -stabilized bis(lithiomethyl)silanes was performed by the reductive cleavage of C-S bonds with electron transfer reagents. Bis[(phenylthio)methyljsilanes synthesized by the reaction of dichlorosilanes with [(phenylthio)methyljlithium were transformed to the corresponding bis(lithiomethyl)silanes 7 by reaction with lithium naphthalenide (LiCiUHB) or lithium p,p'-di-(er/-butylbiphenylide (LiDBB) as an electron transfer reagent and were characterized by their reaction with Bu3SnCl. The C-S bonds of bis[(phenylthio)methyl]silanes can be cleaved selectively making possible the introduction of two different groups. -The silicon atom plays a central role in the reactivity of the presented structural types. The bis(lithiomethyl)silanes are used as new building blocks for the preparation of organosilanes, Si-H-functionalized organosilanes, and 1,3-disilacyclobutanes containing SiCH2Si structural units. VCH Verlagsgesellschaft mbH, 1996.