18077-42-4 Usage
Uses
Used in Synthetic Organic Chemistry:
TRIS(TRIMETHYLSILYLMETHYL)PHOSPHINE is used as a reducing agent for facilitating the reduction of functional groups such as ketones, aldehydes, and alkyl halides, enhancing the efficiency and selectivity of various chemical reactions.
Used in Coordination Chemistry:
In coordination chemistry, TRIS(TRIMETHYLSILYLMETHYL)PHOSPHINE serves as a ligand, contributing to the stabilization and modification of metal catalysts, which is essential for optimizing catalytic processes.
Used in Pharmaceutical Synthesis:
TRIS(TRIMETHYLSILYLMETHYL)PHOSPHINE is utilized as a key intermediate in the synthesis of various pharmaceuticals, playing a significant role in the development of new drugs and therapeutic agents.
Used in Agricultural Product Synthesis:
TRIS(TRIMETHYLSILYLMETHYL)PHOSPHINE is also employed in the synthesis of agricultural products, contributing to the production of effective and innovative agrochemicals for crop protection and enhancement.
Used in Laboratory and Industrial Settings:
Due to its diverse applications, TRIS(TRIMETHYLSILYLMETHYL)PHOSPHINE is a valuable chemical in both laboratory research and industrial applications, where it aids in the advancement of chemical processes and product development.
Check Digit Verification of cas no
The CAS Registry Mumber 18077-42-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,8,0,7 and 7 respectively; the second part has 2 digits, 4 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 18077-42:
(7*1)+(6*8)+(5*0)+(4*7)+(3*7)+(2*4)+(1*2)=114
114 % 10 = 4
So 18077-42-4 is a valid CAS Registry Number.
InChI:InChI=1/C12H33PSi3/c1-14(2,3)10-13(11-15(4,5)6)12-16(7,8)9/h10-12H2,1-9H3
18077-42-4Relevant academic research and scientific papers
Transition-Metal Substituted Phosphanes, Arsanes and Stibanes, XXX. Redox Reactions between Triorganodibromophosphoranes or -arsoranes and Transition Metal Anions
Meyer, Angelika,Hartl, Anna,Malisch, Wolfgang
, p. 845 - 850 (2007/10/02)
The reaction of the sodium carbonyl metalate Na with the phosphorane (Me3SiCH2)3PBr2 results in the formation of (Me3SiCH2)3P and Cp(CO)3WBr or 2 respectively, depending on the solvent used.The redox reactions between Na and the arsenic analogue (RCH2)3AsBr2 (R = Ph, Me3Si) yield the products Cp(CO)3MoBr and (RCH2)3As.A mechanism involving radicals is discussed.At elevated temperatures the products react further to give the square pyramidal complexes cis-Cp(CO)2MBr (1,2a,b) with loss of CO.In an analogous manner Cp(CO)3MBr (M = Mo, W) and (RCH2)3E (E = As, Sb) afford compounds cis-Cp(CO)2MBr (2c, 3).The dynamic behaviour of the chiral complexes 1, 2a, b, was investigated by 1H NMR spectroscopy. - Key words: Transition Metal Nucleophiles, Redox Reaction, Stereospecific CO-Substitution, Dynamic Behaviour
