180778-36-3

Upstream product

• 24850-33-7 allyltributylstanane 
• 3068-34-6 Acetic acid (2R,3S,4R,5R,6R)-3-acetoxy-2-acetoxymethyl-5-acetylamino-6-chloro-tetrahydro-pyran-4-yl ester 
• 108-24-7 acetic anhydride 
• 262286-48-6 3-(2'-N-acetylamino-3',4',6'-tri-O-benzyl-2'-deoxy-α-D-glucopyranosyl)-1-propene 

Downstream Products

• 1065524-59-5 3-(2-acetamido-4,6-O-benzylidene-2-deoxy-α-D-glucopyranosyl)propene 
• 266360-22-9 diethyl (4-acetamido-3,7-anhydro-5,6,8-tri-O-benzyl-1,2,4-trideoxy-D-glycero-D-ido-octitol-1-yl)phosphonate 
• 266360-20-7 (4-acetamido-3,7-anhydro-5,6,8-tri-O-benzyl-2,4-dideoxy-D-glycero-D-ido-octitol-1-yl) phosphate 
• 266360-19-4 4-acetamido-3,7-anhydro-5,6,8-tri-O-benzyl-2,4-dideoxy-D-glycero-D-ido-octitol 
• 266360-21-8 4-acetamido-3,7-anhydro-5,6,8-tri-O-benzyl-1-bromo-1,2,4-trideoxy-D-glycero-D-ido-octitol 
• 262286-55-5 4-((2R,3S,4R,5S,6R)-3-Acetylamino-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-N-[(2R,3R,4R,5R)-3,4-bis-benzyloxy-5-(2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-tetrahydro-furan-2-ylmethyl]-2,3-dihydroxy-butyramide 

Relevant academic research and scientific papers

Regioselective debenzylation of C-glycosyl compounds by boron trichloride

Boron trichloride has been found to promote selective deprotection of 1,2- or 1,3-cis oriented secondary benzyl ethers of per-benzylated C-glycosyl derivatives. The reactivity towards BCl3 follows the order: C-4 ≥ C-2 > C-6 > C-3 for C-glucopyranosyl derivatives and C-3 ≥ C-4 > C-6 > C-2 for C-galactopyranosyl derivatives. Preparatively useful selective debenzylation at secondary positions was possible after careful control of reaction conditions.

Stereocontrolled allylation of 2-amino-2-deoxy sugar derivatives by a free-radical procedure

Preparative routes for anomerically specific 1-C-allylation of 2-amino-2-deoxy sugars have been evaluated in a comparative study of various N-substituents and aglycons as precursors for glycosyl radicals that effectively capture an allyl group from allylt