180782-75-6

Basic information

• Product Name: 1-(methoxycarbonyl)pentadec-10(S)-yl O-(2,3-di-O-acetyl-4,6-O-benzylidene-β-D-glucopyranosyl)-(1->2)-3,4-O-isopropylidene-β-D-fucopyranoside
• Synonyms: 1-(methoxycarbonyl)pentadec-10(S)-yl O-(2,3-di-O-acetyl-4,6-O-benzylidene-β-D-glucopyranosyl)-(1->2)-3,4-O-isopropylidene-β-D-fucopyranoside
• CAS NO: 180782-75-6
• Molecular Weight: 806.989
• Mol File: 180782-75-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1-(methoxycarbonyl)pentadec-10(S)-yl O-(2,3-di-O-acetyl-4,6-O-benzylidene-β-D-glucopyranosyl)-(1->2)-3,4-O-isopropylidene-β-D-fucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(methoxycarbonyl)pentadec-10(S)-yl O-(2,3-di-O-acetyl-4,6-O-benzylidene-β-D-glucopyranosyl)-(1->2)-3,4-O-isopropylidene-β-D-fucopyranoside(180782-75-6)
• EPA Substance Registry System: 1-(methoxycarbonyl)pentadec-10(S)-yl O-(2,3-di-O-acetyl-4,6-O-benzylidene-β-D-glucopyranosyl)-(1->2)-3,4-O-isopropylidene-β-D-fucopyranoside(180782-75-6)

Safety Data

• Hazardous Substances Data: 180782-75-6(Hazardous Substances Data)

Upstream product

• 180782-63-2 1-(methoxycarbonyl)pentadec-10(S)-yl 3,4-O-isopropylidene-β-D-fucopyranoside 
• 180782-72-3 2,3-di-O-acetyl-4,6-O-benzylidene-α-D-glucopyranose 1-trichloroacetimidate 
• 197853-38-6 ethyl 2,3-di-O-acetyl-4,6-O-benzylidene-1-thio-β-D-glucopyranoside 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 7404-35-5 1,2,3,4-tetra-O-acetyl-6-deoxy-α-D-galactopyranose 
• 32934-24-0 ethyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranoside 
• 7473-36-1 ethyl 1-thio-β-D-glucopyranoside 
• 197915-84-7 3,4-O-isopropylidene-2-O-pivaloyl-α-D-fucopyranose 
• 197853-45-5 1-(methoxycarbonyl)pentadec-10(S)-yl 2,3,4-tri-O-acetyl-β-D-fucopyranoside 
• 197853-43-3 1-(tert-butyldimethylsiloxy)-11(S)-hexadecanyl acetate 
• 197853-44-4 11(S)-acetoxy-1-hexadecanoic acid 
• 197853-42-2 1-(tert-butyldimethylsiloxy)-11(S)-hexadecanol 
• 180980-45-4 acetyl 2,3-di-O-acetyl-4,6-O-benzyliden-D-glucopyranoside 
• 180782-60-9 methyl (11S)-11-[(3,4-O-isopropylidene-2-O-pivaloyl-β-D-fucopyranosyl)oxy]hexadecanoate 

Downstream Products

• 180782-81-4 (S)-1-(hydroxycarbonyl)pentadec-10-yl O-(4,6-O-benzylidene-β-D-glucopyranosyl)-(1->2)-3,4-O-isopropylidene-β-D-fucopyranoside 1,3-(B)-lactone 
• 197916-06-6 methyl (11S)-11-[[(3-O-acetyl-4,6-O-benzylidene-β-D-glucopyranosyl)-(1->2)-3,4-O-isopropylidene-β-D-fucopyranosyl]oxy]hexadecanoate 
• 197916-04-4 methyl (11S)-11-[[(4,6-O-benzylidene-β-D-glucopyranosyl)-(1->2)-3,4-O-isopropylidene-β-D-fucopyranosyl]oxy]hexadecanoate 
• 180782-78-9 1-(hydroxycarbonyl)pentadec-10(S)-yl O-(4,6-O-benzylidene-β-D-glucopyranosyl)-(1->2)-3,4-O-isopropylidene-β-D-fucopyranoside 

Relevant articles and documents

The First Total Synthesis of Tricolorin A

Keywords: glycosylations; macrocycles; one-pot reactions; total synthesis; tricolorin A

Total synthesis of tricolorin A

Tricolorin A (1) is a novel tetrasaccharide macrolactone that is a natural herbicide. In this paper is reported a total synthesis of 1. Coupling of hydroxy ester 18 with D-fucosyl trichloroacetimidate 23 gave fucoside 24. Removal of he C-2 pivaloyl group