180784-55-8

Basic information

• Product Name: Benzyl-[9-(benzyl-ethoxy-phosphinoylmethyl)-[1,10]phenanthrolin-2-ylmethyl]-phosphinic acid ethyl ester
• CAS NO: 180784-55-8
• Molecular Weight: 572.58
• Mol File: 180784-55-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzyl-[9-(benzyl-ethoxy-phosphinoylmethyl)-[1,10]phenanthrolin-2-ylmethyl]-phosphinic acid ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzyl-[9-(benzyl-ethoxy-phosphinoylmethyl)-[1,10]phenanthrolin-2-ylmethyl]-phosphinic acid ethyl ester(180784-55-8)
• EPA Substance Registry System: Benzyl-[9-(benzyl-ethoxy-phosphinoylmethyl)-[1,10]phenanthrolin-2-ylmethyl]-phosphinic acid ethyl ester(180784-55-8)

Safety Data

• Hazardous Substances Data: 180784-55-8(Hazardous Substances Data)

Upstream product

• 36103-43-2 diethyl benzylphosphonite 
• 78831-37-5 2,9-bis-(bromomethyl)-1,10-phenantroline 
• 78831-36-4 1,10-phenanthroline-2,9-dimethanol 

Relevant articles and documents

Synthesis and solution complexation behaviour of tetradentate diamines with hard phosphinate donors

Seven acyclic tetradentate compounds of varying lipophilicity incorporating two nitrogen and two alkyl or aryl phosphinate donors have been prepared and their complexation of divalent ions has been studied in aqueous solution by pH-metric, NMR and electrospray mass spectrometric methods of analysis. The hard phosphinate oxygen donor favours binding to the charge-dense Mg2+ ion but binds copper(II) only very weakly in solution. Nickel and zinc ions do form 1:1 complexes involving significant phosphinate ligation and this donor-atom preference leads to an inversion of the Irving-Williams stability sequence.