180794-48-3

Upstream product

• 12093-13-9 η6-para-xylene molybdenum(0) tricarbonyl 
• 99248-93-8 {(1,2-eta.2)-1,3,5,7-cycloheptatetraene}bis(triphenylphosphine)platinum⁽⁰⁾ 

Relevant academic research and scientific papers

Preparation and fluxionality of a bimetallic platinum-molybdenum complex of 1,2,4,6-cycloheptatetraene

Fluxionality in the (Ph3P)2Pt l Mo(CO)3 complex of 1,2,4,6-cycloheptatetraene, 2, is rapid at 20 °C. The process is intramolecular (determined by selective isotopomer irradiation) and requires simultaneous movement of both metals concomitant with inversion of the allene moiety. Fluxionality in the mononuclear complex, 1 is intramolecular at 60 °C but has a superimposed intermolecular component at 80 °C.