180802-01-1

Basic information

• Product Name: DIPHENYL SULFIDE-D10
• Synonyms: DIPHENYL SULFIDE-D10
• CAS NO: 180802-01-1
• Molecular Formula: C12D10S
• Molecular Weight: 196.33
• Product Categories: Alphabetical Listings;D;Stable Isotopes
• Mol File: 180802-01-1.mol
• Article Data: 1

Chemical Properties

• Melting Point: -40 °C(lit.)
• Boiling Point: 296 °C(lit.)
• Flash Point: 113 °C
• Appearance: /
• CAS DataBase Reference: DIPHENYL SULFIDE-D10(CAS DataBase Reference)
• NIST Chemistry Reference: DIPHENYL SULFIDE-D10(180802-01-1)
• EPA Substance Registry System: DIPHENYL SULFIDE-D10(180802-01-1)

Safety Data

• Hazard Codes: Xn,N
• Statements: 22-38-50/53
• Safety Statements: 23-28-60-61
• RIDADR: UN 3082 9/PG 3
• Hazardous Substances Data: 180802-01-1(Hazardous Substances Data)

Usage

Uses

Diphenyl-d10 Sulfide (CAS# 180802-01-1) is a useful isotopically labeled research compound.

Upstream product

• 4165-57-5 bromobenzene-d5 

Relevant articles and documents

Synthesis of α-Aryl Primary Amides from α-Silyl Nitriles and Aryl Sulfoxides through [3,3]-Sigmatropic Rearrangement

A simple and efficient protocol was developed for the preparation of challenging α-aryl primary amides. This metal-free coupling process was triggered by TfOH-promoted electrophilic activation of α-silyl nitrile to generate keteniminium ion species, followed by reaction with aryl sulfoxide through [3,3]-sigmatrophic rearrangement to provide the target product. To the best of our knowledge, α-silyl nitrile has been rarely used as a pro-electrophilic reagent. Computational investigations confirmed the transient existence of a highly electrophilic keteniminium intermediate.