180853-33-2Relevant academic research and scientific papers
An improved oxidation method for the synthesis of azodicarbonyl compounds
Starr, Jeremy T.,Rai, Gurdev S.,Dang, Hung,McNelis, Brian J.
, p. 3197 - 3200 (1997)
Five representative hydrazo compounds have been oxidized in high yield using Br2 and pyridine. Yields range from 80% to 93%. For the synthesis of dibenzyl azodicarboxylate, this process produced analytically pure material directly from the reaction mixture.
Synthesis and ene reactions of di-(-)-methyl diazenedicarboxylate
Brimble, Margaret A.,Heathcock, Clayton H.,Nobin, Gregory N.
, p. 2007 - 2016 (2007/10/03)
The preparation of di-(-)-menthyl diazendicarboxylate 3 is described. Reaction of hydrazine with excess (-)-menthyl chloroformate 1 afforded dimenthyl diazanedicarboxylate 2 which was then oxidized to the azo-enophile 3. The azo-ene reactions of 3 with th
