180891-50-3

Basic information

• Product Name: (4-fluorophenyl)Pd(P(4-methoxyphenyl)3)2I
• CAS NO: 180891-50-3
• Molecular Weight: 1033.16
• Mol File: 180891-50-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4-fluorophenyl)Pd(P(4-methoxyphenyl)3)2I(CAS DataBase Reference)
• NIST Chemistry Reference: (4-fluorophenyl)Pd(P(4-methoxyphenyl)3)2I(180891-50-3)
• EPA Substance Registry System: (4-fluorophenyl)Pd(P(4-methoxyphenyl)3)2I(180891-50-3)

Safety Data

• Hazardous Substances Data: 180891-50-3(Hazardous Substances Data)

Upstream product

• 1271-03-0 allyl(cyclopentadiene)palladium(II) 
• 352-34-1 4-fluoro-1-iodobenzene 
• 855-38-9 P(p-CH₃OC₆H₄)3 

Downstream Products

• 200267-29-4 Pd[I(C₆H₄(F))(P(C₆H₄(OCH₃))3)2] 

Relevant articles and documents

New methods for the synthesis of ArPdL2I (L = tertiary phosphine) complexes

Organopalladium ArPdL2I (L = tertiary phosphine) complexes (1) can be synthesized in one step from the precursors Pd2(dba)3·C6H6 (2) (dba = t,t-dibenzylideneacetone) and (η3-allyl)PdCp (3) (Cp = η5-cyclopentadienide). Two advantages over previous synthetic methods are that this route requires only stoichiometric amounts of phosphine and that the desired complexes are easily isolated from reaction byproducts. The scope and generality of these reactions are investigated, and the synthesis of a number of new organic- and water-soluble complexes utilizing this methodology is discussed. Improved syntheses of water-soluble ligands P(C6H5)2(4-SO3KC6H 4) (5) and As(C6H5)2(4-SO3KC6H 4) (6) are presented as well.