180907-59-9Relevant academic research and scientific papers
High catalytic activity and selectivity in hydrosilylation of new Pt(II) metallosupramolecular complexes based on ambidentate ligands
Walczak, Anna,Stachowiak, Hanna,Kurpik, Gracjan,Ka?mierczak, Joanna,Hreczycho, Grzegorz,Stefankiewicz, Artur R.
, p. 139 - 146 (2019)
Two new air- and water-stable Pt(II) metallosupramolecular complexes based on ambidentate ligands have been designed, synthesized and fully characterized. The structure of complexes has been determined by various analytical techniques including NMR spectroscopy and TOF-MS. Additionally, the single crystal structure of 2 was determined by X-ray diffraction. The catalytic activity of these complexes in hydrosilylation has been investigated, establishing that both have similar high activity and selectivity within a broad scope of structurally distinct olefins and hydrosilanes.
METHOD FOR PRODUCING ORGANOSILICON COMPOUND BY HYDROSILYLATION WITH METALLIC-ELEMENT-CONTAINING NANOPARTICLES
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Paragraph 0091-0093; 0096, (2019/11/21)
An organosilicon compound can be efficiently produced by using metallic element-containing nanoparticles such as a platinum element-containing nanoparticle having a solvent on surface as a catalyst of the hydrosilylation reaction of alkenes.
Ni-catalyzed hydroboration and hydrosilylation of olefins with diboron and silylborane
Kamei, Toshiyuki,Nishino, Sohshi,Shimada, Toyoshi
supporting information, p. 2896 - 2899 (2018/06/18)
Herein we report a Ni-catalyzed formal hydroboration of olefins, which afforded anti-Markovnikov-type alkylboranes with B2pin2 and a stoichiometric amount of water. Formal hydrosilylation using air- and moisture-sensitive silylborane
Desulfurizative silation, germation, and stannation of thioacetals and their analogues utilizing titanocene(II)
Takeda, Takeshi,Nozaki, Naoki,Fujiwara, Tooru
, p. 3533 - 3536 (2007/10/03)
Desulfurization of thioacetals with the low valent titanium species CP2Ti[P(OEt)3]2 in the presence of trialkylsilanes afforded the corresponding tetraalkylsilanes. Allylsilanes were obtained regioselectively using β,γ-uns
