180971-12-4Relevant academic research and scientific papers
Formation of oxoborane and thioxoborane from a dithiastannaboretane derivative
Ito, Mitsuhiro,Tokitoh, Norihiro,Okazaki, Renji
, p. 533 - 536 (1997)
Reaction with an oxygen-donating reagent such as DMSO and thermolysis of a 1,3,2,4-dithiastannaboretane derivative bearing 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl (Tbt) group led to the formation of novel boron-group 16 element double bond compounds, oxoborane (Tbt-B=O) and thioxoborane (Tbt-B=S). The oxoborane and thioxoborane underwent cycloaddition reactions to give the corresponding adducts in good yields.
