180976-45-8Relevant academic research and scientific papers
Microwave-assisted silyloxy-cope rearrangement of syn-aldol products in DMF: Enhancement of rate and diastereoselectivity
Schneider, Christoph,Khaliel, Souad
, p. 1413 - 1415 (2006)
Microwave-assisted Cope rearrangements of 1,5-dienes embedded in a syn-aldol structure proceed in substantially reduced reaction times and markedly increased diastereoselectivity when conducted in DMF as solvent. Georg Thieme Verlag Stuttgart.
Silyloxy-cope rearrangement of chiral aldol adducts
Black, W. Cameron,Giroux, Andre,Greidanus, Grace
, p. 4471 - 4474 (2007/10/03)
The silyloxy-Cope rearrangement of a chiral 1,5-diene generated from aldol condensation proceeds in high yield and selectivity under mild thermal conditions to generate a new stereocenter five atoms removed from the chiral auxiliary.
