180985-37-9

Basic information

• Product Name: Carbamic acid, (4-cyano-1-methylbutyl)-, ethyl ester (9CI)
• Synonyms: Carbamic acid, (4-cyano-1-methylbutyl)-, ethyl ester (9CI)
• CAS NO: 180985-37-9
• Molecular Formula: C9H16N2O2
• Molecular Weight: 0
• Mol File: 180985-37-9.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Carbamic acid, (4-cyano-1-methylbutyl)-, ethyl ester (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, (4-cyano-1-methylbutyl)-, ethyl ester (9CI)(180985-37-9)
• EPA Substance Registry System: Carbamic acid, (4-cyano-1-methylbutyl)-, ethyl ester (9CI)(180985-37-9)

Safety Data

• Hazardous Substances Data: 180985-37-9(Hazardous Substances Data)

Upstream product

• 107-13-1 acrylonitrile 

Relevant articles and documents

β-NITROGENATED RADICALS IN ORGANIC SYNTHESIS: REACTIONS WITH ELECTROPHILIC OLEFINS

The reaction of iodoamide 1a or iodocarbamates 1b,c with electrophilic olefins 2a-e and in situ generated tributyltin hydride (from tributyltin chloride in a substoichiometric amout and an excess of sodium borohydride) in the presence of a catalytic amount of AIBN in dry ethanol at 0 to 20 deg C yields, after treatment with aqueous sodium fluoride, the expected coupling products 3aa-ce in moderate yields.Compounds 4a-c resulting from an iodine/hydrogen exchange in the starting materials 1a-c are also obtained as by-products in variable amounts.Parablas Clave: radicales β-funcionalizados, yodoamidas, formacion de enlaces C-C