181017-91-4Relevant academic research and scientific papers
A facile regio- and stereocontrolled synthesis of (Z)-1,3-enylnylselenides via cross coupling of (E)-α-iodovinylselenides with terminal alkynes
Zhong, Ping,Huang, Nanping
, p. 139 - 145 (2007/10/03)
(Z)-1,3-Enylnylselenides were conveniently obtained under mild condition via the cross coupling of the corresponding (E)-α-iodovinylselenides with terminal alkynes in the presence of Pd(PPh3)4 and CuBr.
Addition of hydrogen halides to acetylenic selenides. Synthesis of 1- halo-1-selenoalkenes
Comasseto, Joao V.,Menezes, Paulo H.,Stefani, Helio A.,Zeni, Gilson,Braga, Antonio L.
, p. 9687 - 9702 (2007/10/03)
Acetylenic selenides react with HX (X=Cl, Br, I) at room temperature to give 1-halo-1-selenoalkenes in good yields The 1-iodo-1-selenoalkenes were transformed into the corresponding vinylic organometallics (M=Zn, Cu, Cr).
