18102-34-6Relevant academic research and scientific papers
α-Halogenation as a Strategy to Functionalize Cyclohexa-2,4-dienones
Chittimalla, Santhosh Kumar,Koodalingam, Manikandan,Gadi, Vinod Kumar,Anaspure, Prasad
, p. 475 - 480 (2017/02/24)
A facile pyridine-mediated α-halogenation approach to functionalize cyclohexa-2,4-dienones is developed. A range of reactions, including organometallic coupling protocols, have been applied on these newly obtained halogenated cyclohexa-2,4-dienones, and the results are presented herein.
Efficient and green telescoped process to 2-methoxy-3-methyl-[1,4] benzoquinone
Rodriguez Gonzalez, Raquel,Gambarotti, Cristian,Liguori, Lucia,Bjorsvik, Hans-Rene
, p. 1703 - 1706 (2007/10/03)
A telescoped process for the preparation of 2-methoxy-3-methyl-[1,4] benzoquinone is disclosed. When this novel process is compared to the prevailing method that utilizes Na2Cr2O7 as the oxidant, the novel process represen
ON THE METALATION OF PHENOLIC COMPOUNDS: READY ACCESS TO HIGHLY SUBSTITUTED PHENOLS.
Costa, Antonio,Saa, Jose M.
, p. 5551 - 5554 (2007/10/02)
The direct metalation of several p-hydroxybenzylmethyl ethers has been studied.Those substrates possesing an electron-withdrawing group in a 1,3 relationship with the coordinating (-CH2OMe) group underwent regioselective metalation by the action of n-BuLi/THF.Highly substituted phenols can thus be readily prepared.
