18105-48-1Relevant academic research and scientific papers
Pd-catalyzed coupling reaction of allyl and propargyl ethers with chlorosilanes
Naitoh, Yoshitaka,Bando, Fumiaki,Terao, Jun,Otsuki, Kazutaka,Kuniyasu, Hitoshi,Kambe, Nobuaki
, p. 236 - 237 (2008/02/04)
Pd-catalyzed synthesis of allylsilanes from chlorosilanes and allyl ethers is described. The reaction proceeds efficiently at room temperature by the use of phenyl or vinyl Grignard reagent in the presence of palladium catalysts. The present method can also be applied to synthesis of propargylsilanes by the use of propargyl ethers. Copyright
Titanocene-catalyzed formation of allylsilanes from allyl ethers and chlorosilanes
Nii, Shinsuke,Terao, Jun,Kambe, Nobuaki
, p. 1699 - 1702 (2007/10/03)
A new method for silylation of allyl ethers with chlorosilanes has been developed by the use of Cp2TiCl2 as a catalyst. This reaction proceeds efficiently at -20°C in THF using nBuMgCl. A plausible reaction pathway via allyltitanocene intermediate was proposed.
