18106-48-4

Basic information

• Product Name: Silanamine, 1,1,1-triethyl-N-phenyl-
• CAS NO: 18106-48-4
• Molecular Formula: C12H21NSi
• Molecular Weight: 207.391
• Mol File: 18106-48-4.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Silanamine, 1,1,1-triethyl-N-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silanamine, 1,1,1-triethyl-N-phenyl-(18106-48-4)
• EPA Substance Registry System: Silanamine, 1,1,1-triethyl-N-phenyl-(18106-48-4)

Safety Data

• Hazardous Substances Data: 18106-48-4(Hazardous Substances Data)

Upstream product

• 2117-17-1 triethylsilylamine 
• 62-53-3 aniline 
• 994-30-9 triethylsilyl chloride 
• 2117-19-3 1,1,1-Trimethyl-3,3,3-triaethyl-disilazan 
• 103-71-9 phenyl isocyanate 
• 617-86-7 triethylsilane 
• 622-37-7 Phenyl azide 

Downstream Products

• 994-30-9 triethylsilyl chloride 
• 1112-49-8 triethylsilyl iodide 
• 18416-20-1 et3Si{NH(et-1-ph)} 
• 17911-34-1 triethyl-(1-methyl-2-phenyl-ethylamino)-silane 
• 17082-53-0 triethyl-benzylamino-silane 
• 6022-10-2 (diethylamino)triethylsilane 

Relevant articles and documents

N-Silylation of Amines Mediated by Et3SiH/KOtBu

Silylation of primary and secondary amines is reported, using triethylsilane as the silylating reagent in the presence of potassium tert-butoxide (KOtBu). The reaction proceeds well in the presence of 0.2 equiv. of KOtBu. In competit

Palladium nanoparticles supported on graphene as catalysts for the dehydrogenative coupling of hydrosilanes and amines

Palladium nanoparticles (Pd NPs) were supported on undoped and N- or B-doped graphenes (Gs) and these materials have been used as catalysts for the dehydrogenative coupling of hydrosilanes and amines to form silazanes. Working under optimal conditions, a conversion over 99% and a selectivity of 84% were achieved for the reaction of dimethylphenylsilane with morpholine. In contrast, copper (Cu NPs) or nickel nanoparticles (Ni NPs) supported on G did not promote the formation of the corresponding Si-N coupling product. It was found that Pd/G performed better for this coupling than analogous catalysts, in which Pd NPs were supported on active carbon, multiwall carbon nanotubes or diamond NPs. Pd/G as a catalyst has a wide substrate scope, including aliphatic and aromatic amines and mono or dihydrosilanes. Pd/G undergoes a gradual deactivation due to the growth and partial agglomeration of Pd NPs and the aggregation of G sheets, as observed by TEM. This journal is

Radical reduction of aromatic azides to amines with triethylsilane

Aromatic azides are inert toward triethylsilane under thermal conditions in the presence of a radical initiator, but in the presence of additional catalytic amounts of tert-dodecanethiol, they afford anilinosilanes and thence the corresponding anilines in virtually quantitative yields.