181060-03-7

Basic information

• Product Name: Cyclohexanecarboxaldehyde, 1-(methylthio)- (9CI)
• Synonyms: Cyclohexanecarboxaldehyde, 1-(methylthio)- (9CI)
• CAS NO: 181060-03-7
• Molecular Formula: C₈H₁₄OS
• Molecular Weight: 158.26116
• Product Categories: ALDEHYDE
• Mol File: 181060-03-7.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Cyclohexanecarboxaldehyde, 1-(methylthio)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanecarboxaldehyde, 1-(methylthio)- (9CI)(181060-03-7)
• EPA Substance Registry System: Cyclohexanecarboxaldehyde, 1-(methylthio)- (9CI)(181060-03-7)

Safety Data

• Hazardous Substances Data: 181060-03-7(Hazardous Substances Data)

Upstream product

• 5813-48-9 Methanesulfenyl chloride 
• 53282-55-6 (trimethylsiloxymethylidene)cyclohexane 
• 624-92-0 Dimethyldisulphide 
• 32368-19-7 1,2-diphenyl-2-methylthio-1-ethanone 
• 2043-61-0 cyclohexanecarbaldehyde 
• 3289-28-9 ethyl cyclohexanecarboxylate 

Downstream Products

• 711028-55-6 (E)-4-(1-Methylsulfanyl-cyclohexyl)-but-3-en-2-ol 
• 711028-40-9 (E)-4-(1-Methylsulfanyl-cyclohexyl)-but-3-en-2-one 

Relevant articles and documents

Efficient alkylsulfanyl (SMe, SEt and SCH2Ph) and sulfanyl (SH) migration in the stereospecific synthesis of substituted tetrahydrofurans

Treatment of a series of 4-RS-1,3-diols (R = Me, Et, Bn and H) with TsOH in CH2Cl2 gives substituted tetrahydrofurans. We discuss the scope of this reaction using structural variation of the migrating (RS) substituent. All reactions proceeded in high yield and give synthetically useful products.

Do the electronic effects of sulfur indeed control the π-selectivity of γ-sulfenyl enones? An investigation

The electronic effects of sulfur in γ-sulfenyl enones are not transmitted to the carbonyl carbon through the π bond as reported previously. The diastereoselectivity is rather controlled by a combination of several other factors. The steric effects arising